Dinitro­sylbis[tris­(4-fluoro­phen­yl)phosphane]iron chloro­form monosolvate

نویسندگان

  • Myron W. Jones
  • Douglas R. Powell
  • George B. Richter-Addo
چکیده

The title compound, [Fe(NO)(2)(C(18)H(12)F(3)P)(2)]·CHCl(3), belongs to the family of metal dinitrosyl compounds with the general formula Fe(NO)(2)(L)(x), referred to collectively as 'dinitrosyl iron compounds' (DNICs). Herein we report the structure of a dinitrosyl iron diphosphane complex, (Fe(NO)(2)L(2), with L = P(C(6)H(4)-p-F)(3). The structure includes one metal complex mol-ecule and one chloro-form solvent mol-ecule. The iron atom is tetra-hedrally coordinated with two phosphane ligands and with two NO groups with Fe-N-O angles of 178.1 (2) and 177.0 (2)°.

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Dinitro­sylbis[tris­(4-chloro­phen­yl)phosphane]iron

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011